A Multifunctional Dysprosium‐Carboxylato 2D Metall–Organic Framework
Jonay González, Pablo Sevilla, Guillem Gabarró‐Riera, Jesús Jover, Jorge Echeverría, Sara Fuertes, Ana Arauzo, Elena Bartolomé, E. Carolina Sañudo
Abstract
Abstract We report the microwave assisted synthesis of a bidimensional (2D) MOF of formula [Dy(MeCOO)(PhCOO) 2 ] n ( 1 ) and its magnetically diluted analogue [La 0.9 Dy 0.1 (MeCOO)(PhCOO) 2 ] ( 1 d ). 1 is a 2D material with single‐ion‐magnet (SIM) behaviour and 1 d is a multifunctional, magnetic and luminescent 2D material. 1 can be exfoliated into stable nanosheets by sonication.
Topics & Concepts
DysprosiumSonicationMagnetLuminescenceMaterials scienceLanthanideCarboxylateMicrowaveIonCrystallographyChemistryInorganic chemistryStereochemistryOptoelectronicsOrganic chemistryPhysicsChromatographyQuantum mechanicsMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesCrystal Structures and Properties