Design of (β-diazo-α,α-difluoroethyl)phosphonates and their application as masked carbenes in visible light-promoted coupling reactions with sulfonic acids
Haibo Mei, Jiang Liu, Romana Pajkert, Li Wang, Gerd‐Volker Röschenthaler, Jianlin Han
Abstract
A new kind of (β-diazo-α,α-difluoroethyl)phosphonate was designed and used as masked carbenes in visible-light-promoted reactions with sulfonic acids.
Topics & Concepts
DiazoChemistryPhosphonateSulfonic acidVisible spectrumPhotochemistryCombinatorial chemistryOrganic chemistryOptoelectronicsPhysicsFluorine in Organic ChemistryCyclopropane Reaction MechanismsCatalytic C–H Functionalization Methods