Synthesis of High Entropy Carbide Nano Powders <i>via</i> Liquid Polymer Precursor Route
Yanan Sun, Li Ye, Wenying Zhao, Fenghua Chen, Wenfeng Qiu, Weijian Han, Wei Liu, Tong Zhao
Abstract
High entropy carbide ceramics have been proposed in recent years for their promising properties as high hardness, high modulus and low thermal conductivity. Liquid polymer precursor method, of which multiple elements distribute homogeneously during the pyrolysis process, is considered to be favorable in fabricating high entropy ceramics. However, few reports have studied the synthesis of liquid precursor. In this work, liquid polymer precursor of (Ti, Zr, Hf, Ta)C were synthesized by co-hydrolysis and polycondensation of equiatomic metal containing monomers, and adding allyl-functional novolac resin (AN) as carbon source. The obtained polymer precursors of high entropy carbide ceramics (PHECs) were soluble in propyl alcohol and stable for months. The corresponding high