Progress in Transition-Metal-Catalyzed Carbonylative Cycloadditions Using Carbon Monoxide
Chen‐Long Li, Zhi‐Xiang Yu
Abstract
Transition-metal-catalyzed cycloadditions have been evolved as important and efficient methods to construct cyclic molecules.Among them, transition-metal-catalyzed cycloadditions using carbon monoxide (CO) gas as the 1C synthon provide their unique and powerful approaches to build various cyclic molecules within a carbonyl group, which either acts as an important functional group within the cycloadducts, or can be further elaborated to other functional groups.The tremendous advances in this field are introduced.
Topics & Concepts
Carbon monoxideCatalysisTransition metalCarbonylationChemistryPhotochemistryOrganic chemistryAsymmetric Hydrogenation and CatalysisCatalytic C–H Functionalization MethodsCatalytic Alkyne Reactions