Concurrent thiol–ene competitive reactions provide reprocessable, degradable and creep-resistant dynamic–permanent hybrid covalent networks
Qiong Li, Songqi Ma, Na Lü, Jianfan Qiu, Jiale Ye, Yanlin Liu, Sheng Wang, Yingying Han, Binbo Wang, Xiwei Xu, Hongzhi Feng, Jin Zhu
Abstract
A reprocessable, degradable and creep-resistant hybrid network was synthesized through a catalyst-free, solvent-free thiol–ene reaction from two simple components in one pot.
Topics & Concepts
Ene reactionCovalent bondCreepThiolDynamic covalent chemistryChemistryMaterials scienceOrganic chemistryComposite materialMoleculeSupramolecular chemistryCovalent Organic Framework ApplicationsPolymer composites and self-healingSynthetic Organic Chemistry Methods