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Nonconjugated Terpolymer Acceptors with Two Different Fused-Ring Electron-Deficient Building Blocks for Efficient All-Polymer Solar Cells

Wenyan Su, Qunping Fan, Ishita Jalan, Yufei Wang, Wenhong Peng, Tao Guo, Weiguo Zhu, Donghong Yu, Lintao Hou, Ellen Moons, Ergang Wang

2021ACS Applied Materials & Interfaces32 citationsDOIOpen Access PDF

Abstract

, and FF = 55.6%). As a result, the PF1-TS4-60-based all-PSCs achieved a PCE of 9.31%, which is ∼50% higher than the PF1-TS4-based ones (6.17%). The results demonstrate a promising approach to develop high-performance nonconjugated terpolymer acceptors for efficient all-PSCs by means of ternary polymerization using two different A-D-A-structured fused-ring electron-deficient building blocks.

Topics & Concepts

Materials scienceRing (chemistry)PolymerCopolymerPolymer solar cellElectronElectron acceptorChemical engineeringPhotochemistryOrganic chemistryComposite materialEngineeringPhysicsChemistryQuantum mechanicsOrganic Electronics and PhotovoltaicsConducting polymers and applicationsSemiconductor materials and interfaces