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Anatectic melt inclusions in ultra high temperature granulites

Omar Gianola, Omar Bartoli, F. Ferri, Andrea Galli, Silvio Ferrero, Luca S. Capizzi, Christian Liebske, Laurent Rémusat, Stefano Poli, Bernardo Cesare

2020Journal of Metamorphic Geology31 citationsDOIOpen Access PDF

Abstract

Abstract Partial melting up to ultra high temperature (UHT) conditions is one of the major processes for the geochemical differentiation and reworking of the mid‐ to lower continental crust, with relevant implications on its rheological behaviour. UHT granulites from the Gruf Complex (European Central Alps) display garnet and sapphirine porphyroblasts containing a variety of primary melt inclusions (MI). Typically, MI in garnet occur as glassy and polycrystalline inclusions (i.e. nanogranitoids), the latter commonly organized in mm‐sized clusters associated with primary fluid inclusions (FI). Nanogranitoids are characterized by an elliptical faceted shape, with variable sizes ranging from 2 to 115 µm, while glassy inclusions show negative crystal shapes that usually never exceed 15 µm in diameter and present CO 2 ‐rich shrinkage bubbles. The characteristic mineral assemblage observed in nanogranitoids consists of quartz, biotite, muscovite, plagioclase, K‐feldspar, kokchetavite and rarely aluminosilicates. Glassy and re‐homogenized MI are peraluminous and rhyolitic in composition, with SiO 2 = 69 − 80 wt% and Na 2 O + K 2 O = 5 − 12 wt%. Commonly, the analysed MI have very high K 2 O (>6 wt%) and very low Na 2 O (<2 wt%) contents, indicative for potassic to ultrapotassic melts. Measured H 2 O contents of the melts range from 2.9 to 8.8 wt%, whereas CO 2 concentrations are between 160 and 1738 ppm. Accordingly, calculated viscosities for re‐homogenized MI vary between 10 4 and 10 5 Pa·s. Related primary FI mainly contain CO 2 , with rare occurrence of CO and N 2 , and are commonly associated with quartz, as well as different carbonates and phyllosilicates. It is assumed that the source for the carbonic fluid was external and probably related to the degassing lithospheric mantle. Consequently, it is argued that anatexis was initially triggered by incongruent dehydration melting reactions involving biotite breakdown and proceeded in the presence of an externally derived COH‐bearing fluid. The coexistence of COH‐bearing fluid and MI indicates that partial melting occurred under conditions of fluid − melt immiscibility. Potassic to ultrapotassic MI in UHT granulites suggests that lower crustal anatexis may play a significant role in the redistribution of heat‐producing elements (such as K 2 O), potentially influencing the thermal structure of the continental crust.

Topics & Concepts

GranuliteGeologyMuscoviteMelt inclusionsQuartzPartial meltingMineralogyCordieriteBiotiteGeochemistryFluid inclusionsPlagioclaseFeldsparMineralCrystallizationAnalytical Chemistry (journal)Materials scienceCrustFaciesOlivineThermodynamicsChemistryComposite materialMetallurgyChromatographyStructural basinCeramicPhysicsPaleontologyGeological and Geochemical Analysisearthquake and tectonic studiesHigh-pressure geophysics and materials