Tuning magnetic anisotropy by the π-bonding features of the axial ligands and the electronic effects of gold(<scp>i</scp>) atoms in 2D {Co(L)2[Au(CN)2]2}nmetal–organic frameworks with field-induced single-ion magnet behaviour

María A. Palacios, Ismael F. Díaz‐Ortega, Hiroyuki Nojiri, Elizaveta A. Suturina, Mykhaylo Ozerov, J. Krzystek, Enrique Colacio

2020Inorganic Chemistry Frontiers20 citationsDOI Open Access PDF

Abstract

AuIatoms play an important role in determining the anisotropy of CoIInodes in 2D AuI–CoIIfield-induced SIMs.

Topics & Concepts

AnisotropyMagnetic anisotropyChemistryCrystallographyMagnetic fieldPhysicsMagnetizationQuantum mechanicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Organic Frameworks: Synthesis and Applications

Tuning magnetic anisotropy by the π-bonding features of the axial ligands and the electronic effects of gold(<scp>i</scp>) atoms in 2D {Co(L)<sub>2</sub>[Au(CN)<sub>2</sub>]<sub>2</sub>}<sub>n</sub>metal–organic frameworks with field-induced single-ion magnet behaviour

Abstract

Topics & Concepts