Advances in solid lithium ion electrolyte based on the composites of polymer and <scp>LLTO</scp>/<scp>LLZO</scp> of rare earth oxides
Qian Zhang, Kun Liu, Yajing Wen, Yaqi Kong, Yuhao Wen, Qi Zhang, Nailiang Liu, Junpeng Li, Chunjie Ma, Yaping Du
Abstract
Abstract Composite solid electrolyte is a promising solution for the development of new generation of safe and high‐performance all‐solid‐state lithium batteries (ASSLBs). It combines both the advantages of inorganic electrolyte and organic polymer electrolyte, having high ionic conductivity, mechanical strength, good contact with the electrodes and high processability. In the recent decades, rare earth oxides have attracted wide attentions from researchers because of their high ionic conductivity. China is abundant in rare earth resources, so has a good chance to provide the world with high quality rare earth containing functional materials. This review paper focuses on the recent progress in the studies of composite solid electrolyte of polymer and rare earth containing lithium lanthanum zirconium and lithium lanthanum titanium oxides, and gains insights into the challenges in the field, and hopefully helps in the rational design of high performance electrolyte for the development of ASSLBs.