Ultrafast photocurrent hysteresis in photoferroelectric α-In <sub>2</sub> Se <sub>3</sub> diagnosed by terahertz emission spectroscopy
Zhen Lei, Jiawei Chang, Qiyi Zhao, Jian Zhou, Yuanyuan Huang, Qihua Xiong, Xinlong Xu
Abstract
Nonvolatile control over the physical state of polar materials through all-optical methods has been a long-standing objective pursued in optoelectronics. Photoferroelectric semiconductors exhibit immense potential in capturing multimodal nonvolatile states, attributed to their spontaneous and reversible in-plane and out-of-plane polarizations. Herein, we uncover an unprecedented nonvolatile, zero-bias, ultrafast photocurrent hysteresis response with an innovative all-optical approach, discerned by analyzing in-plane and out-of-plane terahertz (THz) waves emitted from photoferroelectric α-In 2 Se 3 . The mechanism underlying such ultrafast photocurrent hysteresis arises from anomalous linear and circular photovoltaic effects synchronously fueled by a localized rearrangement of polarization. By harnessing the anisotropic photoferroelectric kinetics–induced relative phase between the in-plane and out-of-plane polarizations, we further demonstrate the flexible selection of chirality, tunable rotational angle, and optimizable ellipticity of THz waves. Our findings present a unique ultrafast and nondestructive strategy for investigating photoferroelectric hysteresis, empowering dynamic polarization manipulation of THz waves for a wide range of THz applications.