[Bi<sub>6</sub>Mo<sub>3</sub>(CO)<sub>9</sub>]<sup>4−</sup>: a multiple local σ-aromatic cluster containing a distorted Bi<sub>6</sub> triangular prism
Lei Qiao, Dandan Chen, Jun Zhu, Alvaro Muñoz‐Castro, Zhong‐Ming Sun
Abstract
, has been synthesized and structurally characterized. Quantum chemical calculations indicated that the distorted cage cluster features multiple local σ-aromaticity.
Topics & Concepts
Cluster (spacecraft)CrystallographyPhysicsPrismChemistryMaterials scienceAtomic physicsOpticsComputer scienceProgramming languageSynthesis and characterization of novel inorganic/organometallic compoundsOrganoboron and organosilicon chemistryCrystallography and molecular interactions