Hierarchical subcomponent self-assembly of covalent triple-stranded complexes with 3d–4f vertices: luminescence and magnetic properties
Zhi Liu, Fan Yin, Jian Yang, Xiaoqing Guo, Li‐Peng Zhou, Chong‐Bin Tian, Qing‐Fu Sun
Abstract
ions, displaying characteristic luminescence emission in both the visible and near-infrared (NIR) regions. AC susceptibility measurements of 3a'-(Dy, Co) reveal the frequency-independent performance under zero dc field, suggesting the absence of slow relaxation of magnetization. This work offers a new approach for the fabrication of discrete metallic covalent architectures with 3d-4f vertices.
Topics & Concepts
Supramolecular chemistryLanthanideCovalent bondLuminescenceMagnetismChemistryElectrospray ionizationMetal ions in aqueous solutionCrystallographySupramolecular assemblyIonMaterials scienceCrystal structureOrganic chemistryPhysicsOptoelectronicsQuantum mechanicsMetal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesMagnetism in coordination complexes