Molecular Interactions of Diphenhydramine-hydrochloride with Some Imidazolium-Based Ionic Liquids in Aqueous Media at <i>T</i> = 293.15–313.15 K: Volumetric, Acoustic, and UV Absorption Studies
Jeetinder Singh, Manjeet Singh, Samriti Sharma, Shubham Sharma, Meena Sharma
Abstract
) have been calculated. The pair and triplet interaction coefficients are derived from apparent partial molar volumes of transfer. For the present mixtures, the absorption spectra have been also recorded using a UV-visible spectrophotometer. Using Hepler's constant, the structure-making nature of the solute has been confirmed. All these calculated parameters provide detailed insights into various physicochemical interactions prevailing in the ternary system and confirm the presence of a strong attractive interaction between DPH and ILs.
Topics & Concepts
Isentropic processIonic liquidChemistrySpeed of soundMolar volumeC4mimAqueous solutionCompressibilityDiphenhydramine hydrochlorideTernary operationAbsorption (acoustics)ChloridePartial molar propertyThermodynamicsPhysical chemistryAnalytical Chemistry (journal)DiphenhydramineOrganic chemistryMaterials scienceCatalysisInternal medicinePhysicsProgramming languageMedicineComposite materialComputer scienceHistamineIonic liquids properties and applicationsThermodynamic properties of mixturesChemical and Physical Properties in Aqueous Solutions