Zn(II) and Co(II) 3D Coordination Polymers Based on 2-Iodoterephtalic Acid and 1,2-bis(4-pyridyl)ethane: Structures and Sorption Properties
А. S. Zaguzin, Taisiya S. Sukhikh, I. F. Sakhapov, Vladimir P. Fedin, Maxim N. Sokolov⧫, Sergey A. Adonin
Abstract
Metal-organic frameworks [M2(2-I-bdc)2bpe] (M = Zn(II) (1), Co(II) (2), 2-I-bdc = 2-iodoterephtalic acid, and bpe = 1,2-bis(4-pyridyl)ethane) were prepared and characterized by X-ray diffractometry. Both compounds retain their 3D structure after the removal of guest DMF molecules. Selectivity of sorption of different organic substrates from the gas phase was investigated for both complexes.
Topics & Concepts
SorptionSelectivityChemistryMoleculePolymerMetalMetal-organic frameworkInorganic chemistryPhase (matter)Coordination polymerPolymer chemistryOrganic chemistryAdsorptionCatalysisMetal-Organic Frameworks: Synthesis and ApplicationsCrystal structures of chemical compoundsCrystallography and molecular interactions