Effective models for TADF: the role of the medium polarizability
D. K. Andrea Phan Huu, Sangeeth Saseendran, Anna Painelli
Abstract
Building on an effective model Hamiltonian for DMAC–TRZ, a non-adiabatic approach is proposed to estimate (reverse) inter-system crossing rates and to address the role of the polarizability of the matrix in the properties of TADF emitters.
Topics & Concepts
PolarizabilityAdiabatic processHamiltonian (control theory)Materials scienceMatrix (chemical analysis)Chemical physicsQuantum mechanicsPhysicsMathematical optimizationComposite materialMathematicsMoleculeOrganic Light-Emitting Diodes ResearchLanthanide and Transition Metal ComplexesPhotochemistry and Electron Transfer Studies