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Double diffusion for the programmable spatiotemporal patterning of multi-domain supramolecular gels

Hannah S. Cooke, Lisa Schlichter, Carmen C. Piras, David K. Smith

2021Chemical Science31 citationsDOIOpen Access PDF

Abstract

H network formation is better controlled, giving more homogeneous nanoscale structures and stiffer objects. The patterned objects can be further reinforced by the presence of agarose polymer gelator. The shape of the patterning is programmed by both the shape of the central reservoir and the starting geometry in which the reservoirs are organised, with the balance between factors depending on assembly kinetics, as dictated by the choice of acid. This simple methodology therefore enables programming of patterned gels with spatiotemporal control and emergent patterning characteristics.

Topics & Concepts

Supramolecular chemistryDomain (mathematical analysis)DiffusionNanotechnologyComputer scienceMaterials scienceChemistryPhysicsCrystallographyMathematicsCrystal structureThermodynamicsMathematical analysisSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applicationsAdvanced Materials and Mechanics
Double diffusion for the programmable spatiotemporal patterning of multi-domain supramolecular gels | Litcius