Photoinduced double [2 + 2] cycloaddition relay of yne–allenones for highly diastereoselective synthesis of hexacyclic 1-naphthols
Shan‐Shan Zhu, Jiang-Nan Zhou, Quan-Long Wu, Wen‐Juan Hao, Shu‐Jiang Tu, Bo Jiang
Abstract
A new photoinduced photocatalyst-free energy-transfer strategy for double [2 + 2] cycloaddition relay of yne–allenones is reported for the first time and used to produce a series of hitherto unreported hexacyclic 1-naphthols.
Topics & Concepts
ChemistryCycloadditionRelayEnergy transferPhotochemistryCombinatorial chemistryStereochemistryOrganic chemistryCatalysisPhysicsQuantum mechanicsPower (physics)Molecular physicsRadical Photochemical ReactionsOxidative Organic Chemistry ReactionsCatalytic C–H Functionalization Methods