Observation of binding of carbon dioxide to nitro-decorated metal–organic frameworks
Thien D. Duong, Sergey A. Sapchenko, Iván da Silva, Harry G. W. Godfrey, Yongqiang Cheng, Luke L. Daemen, Pascal Manuel, Mark D. Frogley, Gianfelice Cinque, Anibal J. Ramirez‐Cuesta, Sihai Yang⧫, Martin Schröder
Abstract
Synergistic effects between –NO<sub>2</sub> groups and open metal sites lead to optimal binding of CO<sub>2</sub> molecules within MFM-102-NO<sub>2</sub><italic>via</italic> hydrogen bonding to C–H groups.
Topics & Concepts
NitroMetalMoleculeCarbon dioxideOrganic moleculesMetal-organic frameworkChemistryHydrogenInorganic chemistryHydrogen bondPhysical chemistryOrganic chemistryAdsorptionAlkylMetal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysisCovalent Organic Framework Applications