Polyoxometalate-modified reduced graphene oxide foam as a monolith reactor for efficient flow catalysis of epoxide ring-opening reactions
Xiaoting Jing, Zhen Li, Weijie Geng, Hongjin Lv, Yingnan Chi, Changwen Hu
Abstract
A POM@rGO monolith reactor was constructed using a facile and broad-spectrum hydrothermal approach and it effectively catalyzes epoxide ring-opening reactions with 99% conversion and over 90% selectivity, reaching a turnover number (TON) of around 28 044 after 38 h catalysis.
Topics & Concepts
EpoxideMonolithPolyoxometalateCatalysisSelectivityMicroreactorOxideGrapheneRing (chemistry)Hydrothermal circulationChemical engineeringChemistryHydrothermal synthesisMaterials scienceOrganic chemistryNanotechnologyEngineeringPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and ReactionsOxidative Organic Chemistry Reactions