Ligand exchange at tetra-coordinated beryllium centres
Magnus R. Buchner, Dušan Ćoćić, Sergei I. Ivlev, Nils Spang, Matthias Müller, Ralph Puchta
Abstract
Dissociation and ligand exchange processes at mono- and dinuclear beryllium phosphine were studied. This revealed significantly different processes, which are strongly dependent on solvent and ligand and are accountable for their varied reactivity.
Topics & Concepts
ChemistryPhosphineDissociation (chemistry)Ligand (biochemistry)BerylliumHalideCrystallographyNuclear magnetic resonance spectroscopyInorganic chemistryPhysical chemistryStereochemistryMedicinal chemistryOrganic chemistryCatalysisBiochemistryReceptorSynthesis and characterization of novel inorganic/organometallic compoundsCoordination Chemistry and OrganometallicsOrganometallic Complex Synthesis and Catalysis