Asymmetric and zwitterionic Blatter diradicals
Fang Miao, Yu Ji, Bo Han, Sergio Moles Quintero, Hanjiao Chen, Guodong Xue, Lulu Cai, Juan Casado, Yonghao Zheng
Abstract
-isomer (mBP), the zwitterionic form promoted in pBP by the lone-pair electron of the amine nitrogen is not available, yet it possesses a pseudo-hyperconjugation effect where the N lone pair mediates in a bonding coupling in a counter homolytic bond scission mechanism. Both electronic effects converge to promote medium diradical characters and narrow singlet-triplet gaps to the two electronic isomers. All these aspects delineate the subtle balance that shapes the electronic structure of open-shell molecules, which is even more challenging in the case of asymmetric systems, such as those described here with asymmetric phenoxyl-Blatter diradicals.