Construction of hierarchically chiral metal–organic frameworks for fast and mild asymmetric catalysis
Zahra Sharifzadeh, Sayed Ali Akbar Razavi, Ali Morsali
Abstract
Here, CMOF(ASP) is synthesized as a chiral Zr-fumarate framework functionalized with l -aspartate for highly efficient catalysis of ring opening and nitroaldol reactions and asymmetric synthesis of oxazolidinone in mild and green conditions.
Topics & Concepts
CatalysisEnantioselective synthesisRing (chemistry)ChemistryMetal-organic frameworkCombinatorial chemistryNitroaldol reactionMetalOrganocatalysisOrganic chemistryAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsChemical Synthesis and ReactionsPolyoxometalates: Synthesis and Applications