From Waste to Worth: Innovative Pyrolysis of Textile Waste into Microporous Carbons for Enhanced Environmental Sustainability
Anastasia Anceschi, Francesco Trotta, Marina Zoccola, Fabrizio Caldera, Giuliana Magnacca, Alessia Patrucco
Abstract
The generation of synthetic textile waste is a growing global concern, with an unsustainable rate of expansion. This study addresses the growing issue of synthetic textile waste by converting polyester–polyurethane (PET-PU) post-industrial scraps into microporous carbon materials, which can be utilized for wastewater treatment. Using a straightforward pyrolysis process, we achieved a high specific surface area (632 m2/g) and narrow porosity range (2–10 Å) without requiring chemical activation. The produced carbon materials effectively adsorbed methylene blue and orange II dyes, with maximum adsorption capacities of 169.49 mg/g and 147.56 mg/g, respectively. Kinetic studies demonstrated that adsorption followed a pseudo-second-order model, indicating strong interactions between the adsorbent and dyes. Regeneration tests showed that the C-PET-PU could be reused for multiple cycles with over 85% retention of its original adsorption capacity. Preliminary life cycle assessment (LCA) and life cycle cost (LCC) analysis highlighted the environmental and economic advantages of this upcycling approach, showing a reduced global warming potential and a production cost of approximately 1.65 EUR/kg. These findings suggest that transforming PET-PU waste into valuable adsorbents provides a sustainable solution for the circular economy and highlights the potential for broader applications in environmental remediation.