Probing the water adsorption and stability under steam flow of Zr-based metal–organic frameworks using <sup>91</sup>Zr solid-state NMR spectroscopy
Athulya Nadol, Florian Venel, Raynald Giovine, Maëva Leloire, Christophe Volkringer, Thierry Loiseau, Christel Gervais, Caroline Mellot‐Draznieks, Bertrand Doumert, Julien Trébosc, Olivier Lafon, Frédérique Pourpoint
Abstract
The stability of metal–organic frameworks (MOFs) in the presence of water is crucial for a wide range of applications, including the production of freshwater, desiccation, humidity control, heat pumps/chillers and capture and separation of gases.
Topics & Concepts
AdsorptionMetal-organic frameworkNuclear magnetic resonance spectroscopySpectroscopySolid-stateFlow (mathematics)MetalChemistryMaterials scienceSolid-state nuclear magnetic resonanceInorganic chemistryAnalytical Chemistry (journal)Chemical engineeringPhysical chemistryEnvironmental chemistryOrganic chemistryNuclear magnetic resonanceMechanicsPhysicsQuantum mechanicsEngineeringAdvanced NMR Techniques and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsNMR spectroscopy and applications