Germaborenes: Borylene Transfer Agents for the Synthesis of Iminoboranes
Dominik Raiser, Hartmut Schubert, Holger F. Bettinger, Lars Wesemann
Abstract
Halide and phenyl substituted germaborenes were shown to react with azides at room temperature and transfer a borylene moiety to give iminoboranes. This iminoborane synthesis based on a borylene transfer route was investigated computationally in the case of the phenyl substituted germaborene.
Topics & Concepts
MoietyChemistryHalideCombinatorial chemistryStereochemistryPhotochemistryOrganic chemistryOrganoboron and organosilicon chemistryChemical Synthesis and AnalysisCatalytic Cross-Coupling Reactions