Characterization of the first Peacock–Weakley polyoxometalate containing a transplutonium element: curium bis-pentatungstate [Cm(W<sub>5</sub>O<sub>18</sub>)<sub>2</sub>]<sup>9−</sup>
Ian Colliard, Gauthier J.‐P. Deblonde
Abstract
). Single crystal XRD, Raman, and fluorescence characterization show significant differences relative to analogous lanthanide compounds. The study reveals the unsuspected impact of counterions on fluorescence and vibrational modes of the curium complex and its lanthanide counterparts.
Topics & Concepts
CuriumPolyoxometalateChemistryNuclear chemistryRadiochemistryActinideAmericiumOrganic chemistryCatalysisPolyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsNanocluster Synthesis and Applications