Nickel(<scp>ii</scp>) monobenzoporphyrins and chlorins: synthesis, electrochemistry and anion sensing properties
Sandeep Kumar, Nivedita Chaudhri, W. Ryan Osterloh, Karl M. Kadish, Muniappan Sankar
Abstract
generated π-extended porphyrin was also isolated and characterized as to its physicochemical and electrochemical properties and found to possess a narrow electrochemical HOMO-LUMO gap of 1.46 V along with a near-IR (NIR) absorption band located at 861 nm.
Topics & Concepts
MalononitrileChemistryCyanideBathochromic shiftElectrochemistryPorphyrinDeprotonationNickelSubstituentBromideThiophenePhotochemistryMedicinal chemistryStereochemistryIonInorganic chemistryOrganic chemistryFluorescenceElectrodePhysical chemistryCatalysisQuantum mechanicsPhysicsPorphyrin and Phthalocyanine ChemistryMolecular Sensors and Ion DetectionElectrochemical sensors and biosensors