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3D printed different polymer fuel grains for hybrid rocket engine

Xiaodong Yu, Hongsheng Yu, Hongwei Gao, Wei Zhang, Luigi T. DeLuca, Ruiqi Shen

2023FirePhysChem21 citationsDOIOpen Access PDF

Abstract

The advent of various additive manufacturing technologies, such as 3D printing, has changed the structural design and preparation process of rocket fuels. In order to investigate the combustion properties of various common polymer materials that can be additively manufactured by fused deposition, the combustion tests of hybrid rocket fuels prepared by 3D printing were carried out. These materials include polylactic acid (PLA), wood-like polylactic acid (Wood), acrylonitrile-butadiene-styrene (ABS), acrylonitrile-styrene-acrylate (ASA), copolymers of nylon 6 and nylon 6,6 (CoPA), polycarbonate-polybutylene terephthalate (PC-PBT), flame retardant polycarbonate (PC-FR) and polyethylene terephthalateco-1,4-cylclohexylenedimethylene terephthalate (PETG). Thermogravimetric-differential scanning calorimetry (TG-DSC) analysis was carried out on these materials, the printing effect of the fuel grains was observed by three-dimensional X-ray microscopy (μCT) and the combustion performance of these fuels in gaseous oxygen flow (GOX) was recorded by high-speed photography at a constant pressure of 1MPa. The results show that ASA and ABS exhibit good printing results. The regression rates of PC-PBT, PETG, ABS, ASA, CoPA and PLA are 0.792 mm/s, 0.592 mm/s, 0.536 mm/s and 0.477 mm/s, 0.368 mm/s, 0.339 mm/s (AtGox=220kg/(m2·s)), respectively.

Topics & Concepts

Materials scienceAcrylonitrile butadiene styrenePolylactic acidPolycarbonatePolybutylene terephthalateDifferential scanning calorimetryThermogravimetric analysisComposite materialPolymerPolymer chemistryPolyesterChemical engineeringPhysicsThermodynamicsEngineeringRocket and propulsion systems researchEnergetic Materials and CombustionSpace Exploration and Technology
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