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Synthesis of Monolayer Blue Phosphorus Enabled by Silicon Intercalation

Jia Lin Zhang, Songtao Zhao, Shuo Sun, Honghe Ding, Jun Hu, Yuliang Li, Qian Xu, Xiaojiang Yu, Mykola Telychko, Jie Su, Chengding Gu, Yupeng Zheng, Xu Lian, Zhirui Ma, Rui Guo, Jiong Lu, Zhe Sun, Junfa Zhu, Zhenyu Li, Wei Chen

2020ACS Nano81 citationsDOI

Abstract

silicon intercalation of the BlueP-Au alloy on Au(111). The intercalation process is characterized at the atomic scale by low-temperature scanning probe microscopy and further corroborated by synchrotron radiation-based X-ray photoelectron spectroscopy measurements. The evolution of the band structures from the BlueP-Au alloy into Si-intercalated BlueP are clearly revealed by angle-resolved photoemission spectroscopy and further verified by density functional theory calculations.

Topics & Concepts

Intercalation (chemistry)MonolayerSiliconMaterials scienceX-ray photoelectron spectroscopyNanotechnologyDensity functional theoryPhotoemission spectroscopySpectroscopyChemical engineeringOptoelectronicsChemistryInorganic chemistryComputational chemistryPhysicsEngineeringQuantum mechanics2D Materials and ApplicationsGraphene research and applicationsMXene and MAX Phase Materials
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