Litcius/Paper detail

Three-dimensional propagation behavior of hydrogen-related intergranular cracks in high-strength martensitic steel

Akinobu Shibata, I. Gutiérrez‐Urrutia, Akiko Nakamura, Kazuho Okada, Gorō Miyamoto, Yazid Madi, Jacques Besson, Toru Hara, Kaneaki Tsuzaki

2023International Journal of Hydrogen Energy25 citationsDOIOpen Access PDF

Abstract

Using X-ray computed tomography and focused ion beam-scanning electron microscopy (FIB-SEM) serial sectioning, this study investigated the three-dimensional propagation behavior of hydrogen-related intergranular cracks in martensitic steel with a tensile strength of 1.2 GPa, focusing on segments of prior austenite grain boundaries (PAGB segments). X-ray computed tomography revealed that the crack morphology was more continuous in the hydrogen-charged specimens. Through FIB-SEM serial sectioning, we found that crack-tip blunting and ductile rupture of un-cracked ligaments were associated with specific PAGB segments in the uncharged specimen. In the case of hydrogen-related intergranular crack propagation, even very fine, low-angle PAGB segments (sub-micrometer size) can act as obstacles for crack propagation. Based on these results, we propose that the misorientation of each PAGB segment has a large influence on the local arrestability of intergranular crack propagation.

Topics & Concepts

Intergranular corrosionMaterials scienceFocused ion beamMisorientationMartensiteScanning electron microscopeComposite materialHydrogenGrain boundaryUltimate tensile strengthFracture mechanicsIntergranular fractureMetallurgyMicrostructureIonChemistryOrganic chemistryHydrogen embrittlement and corrosion behaviors in metalsMicrostructure and Mechanical Properties of SteelsFatigue and fracture mechanics