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Activator-free single-component Co(<scp>i</scp>)-catalysts for regio- and enantioselective heterodimerization and hydroacylation reactions of 1,3-dienes. New reduction procedures for synthesis of [L]Co(<scp>i</scp>)-complexes and comparison to <i>in situ</i> generated catalysts

Mahesh M. Parsutkar, Curtis E. Moore, T. V. RajanBabu

2022Dalton Transactions16 citationsDOIOpen Access PDF

Abstract

New synthesis of ( L )[Co I X]-complexes from ( L )CoX 2 and Mashima's reagent.

Topics & Concepts

ChemistryCatalysisEnantioselective synthesisHydroacylationActivator (genetics)Combinatorial chemistryStereochemistryOrganic chemistryBiochemistryReceptorRhodiumCatalytic C–H Functionalization MethodsAsymmetric Hydrogenation and CatalysisCatalytic Alkyne Reactions
Activator-free single-component Co(<scp>i</scp>)-catalysts for regio- and enantioselective heterodimerization and hydroacylation reactions of 1,3-dienes. New reduction procedures for synthesis of [L]Co(<scp>i</scp>)-complexes and comparison to <i>in situ</i> generated catalysts | Litcius