Electrocatalytic three-component annulation-halosulfonylation of 1,6-enynes toward 1-indanones using sodium halides as both halogen sources and electrolytes
Tian-Shu Zhang, Wen‐Juan Hao, Rong Wang, Shi‐Chao Wang, Shu‐Jiang Tu, Bo Jiang
Abstract
A new electrochemically induced three-component annulation-halosulfonylation of 1,6-enynes has been developed for stereoselective synthesis of 33 examples of 1-indanones with generally good yields under environmentally benign conditions.
Topics & Concepts
AnnulationHalideHalogenChemistryStereoselectivityComponent (thermodynamics)ElectrolyteCombinatorial chemistrySodiumOrganic chemistryCatalysisElectrodePhysical chemistryAlkylThermodynamicsPhysicsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization MethodsRadical Photochemical Reactions