A covalent deprotection strategy for assembling supramolecular coordination polymers from metal–organic cages
Matthew L. Schneider, Oliver M. Linder‐Patton, Witold M. Bloch
Abstract
metal-organic cage (MOC) composed of amine-protected ligands forms supramolecular coordination polymers (SCPs) upon covalent post-assembly deprotection. The amorphous SCPs form by virtue of aniline-copper coordination and possess a tunable porosity based on the rate of deprotection.
Topics & Concepts
Supramolecular chemistryCovalent bondAnilinePolymerCoordination polymerMetalAmine gas treatingChemistryPolymer chemistryDynamic covalent chemistryAmorphous solidCopperSupramolecular polymersPorosityMaterials scienceCombinatorial chemistryOrganic chemistryMoleculeMetal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesCovalent Organic Framework Applications