Slow magnetic relaxation in Nd(<scp>iii</scp>) and Sm(<scp>iii</scp>) complexes formed in three-dimensional lanthanide-dicyanidometallate(<scp>i</scp>) frameworks exhibiting luminescent properties
Kunal Kumar, Guanping Li, Olaf Stefańczyk, Szymon Chorąży, Koji Nakabayashi, Shin‐ichi Ohkoshi
Abstract
Uncommon lanthanides are used to construct luminescent molecular nanomagnets and a pioneering SMM-based optical thermometer utilizing Sm( iii ) centres.
Topics & Concepts
LanthanideLuminescenceMaterials scienceRelaxation (psychology)ChemistryIonOptoelectronicsOrganic chemistryBiologyNeuroscienceMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies