Mechanosynthesis of ruthenium trisbipyridyl complexes and application in photoredox catalysis in a ball-mill
Florian Luttringer, Matthieu Lavayssiere, Enita Rastoder, Nikita Salov, Tristan Gravelet, François Quintin, Julien Pinaud, Frédéric Lamaty, Xavier Bantreil
Abstract
Ball-milling allowed the efficient preparation of ruthenium complexes with photoredox properties. With a transparent and chemically resistant milling jar in epoxy resin, photoreductive dehalogenation was realized efficiently in a solventless manner.
Topics & Concepts
MechanosynthesisRutheniumBall millMechanochemistryCatalysisPhotoredox catalysisEpoxyMaterials scienceChemistryChemical engineeringNanotechnologyOrganic chemistryPhotocatalysisComposite materialEngineeringRadical Photochemical ReactionsOxidative Organic Chemistry ReactionsCatalytic C–H Functionalization Methods