Development of a novel scorpionate ligand with 6-methylpyridine and comparison of the structural and electronic properties of nickel(<scp>ii</scp>) complexes with related tris(azolyl)borates
Yusuke Fujiwara, Tomoaki Takayama, Jun Nakazawa, Masaya Okamura, Shiro Hikichi
Abstract
A facially-capping tris(6-methylpyridyl)phenylborate is highly electron-donating and its nickel complex is potent m CPBA activator.
Topics & Concepts
Steric effectsTrisChemistryBoronNickelLigand (biochemistry)StereochemistryCombinatorial chemistryOrganic chemistryReceptorBiochemistryMetal complexes synthesis and propertiesOrganometallic Complex Synthesis and CatalysisMetal-Catalyzed Oxygenation Mechanisms