Scalable synthesis of K+/Na+ pre-intercalated α-MnO2 via Taylor fluid flow-assisted hydrothermal reaction for high-performance asymmetric supercapacitors
Thapelo P. Mofokeng, Sebenzile Shabalala, Aderemi B. Haruna, Patrick V. Mwonga, Zikhona N. Tetana, Kenneth I. Ozoemena
Abstract
In this work, a two-step synthetic method: Couette-Taylor flow mixing, and hydrothermal method have been used to synthesize α-manganese oxide pre-intercalated with sodium and potassium ions (Na+/K+@α-MnO2) for supercapacitor application. In addition, the effects of different aqueous electrolytes on the energy storage properties of the Na+/K+@α-MnO2 nanowires are investigated. The results show that KOH is a better electrolyte than NaOH and Na2SO4, with Na+/K+@α-MnO2 nanowires exhibiting a higher specific capacitance of 124 Fg-1 in KOH electrolyte. This is attributed to the high ionic conductivity and smaller hydrate ion of K+ ions. Density functional theory (DFT) calculations were also employed to gain insight into the pseudocapacitance properties of Na+/K+@α-MnO2 nanowires in alkaline electrolytes. DFT calculations revealed that K+ ions have a higher adsorption energy and a higher partial density of states than Na+ ions, indicating more favourable pseudocapacitive behaviour for K+ ions compared to Na+ ions. Furthermore, the asymmetric capacitor device based on N-CNTs@CF//Na+/K+@α-MnO2 delivers a specific energy density of 21 Wh kg−1 and a specific power density of 450 W kg−1, with excellent cycling performance (∼94 % capacity retention after 5,000 cycles). Our findings demonstrate that the pre-intercalation of α-MnO2 nanowires is accountable for enhanced cycling stability, as well as higher capacitance.