A guinea pig for conformer selectivity and mechanistic insights into dissociative ionization by photoelectron photoion coincidence: fluorocyclohexane
Xiangkun Wu, Xiaoguo Zhou, Patrick Hemberger, András Bödi
Abstract
= 11.23 eV. This led us to explore the potential energy surface to find a lower-lying fragmentation channel including H-transfer steps. Rate constant measurements and statistical modeling thus yield fundamental insights into the reaction mechanism beyond what is immediately seen in the mass spectra.
Topics & Concepts
Conformational isomerismChemistryCoincidenceSelectivityDissociativeIonizationComputational chemistryPhotochemistryMoleculeOrganic chemistryIonBiologyPharmacologyMedicineCatalysisAlternative medicinePathologyAdvanced Chemical Physics StudiesMass Spectrometry Techniques and ApplicationsAtmospheric Ozone and Climate