Synthesis, structure, and electrochemical properties of [LNi(R<sub>f</sub>)(C<sub>4</sub>F<sub>8</sub>)]<sup>−</sup> and [LNi(R<sub>f</sub>)<sub>3</sub>]<sup>−</sup> complexes
Scott T. Shreiber, Fatema Amin, Sascha A. Schäfer, Roger E. Cramer, Axel Klein, David A. Vicic
Abstract
The new anionic nickelate complexes [(MeCN)Ni(C 4 F 8 )(CF 3 )] − , [(MeCN)Ni(C 4 F 8 )(C 2 F 5 )] − , [(IMes)Ni(C 4 F 8 )(CF 3 )] − , [(IMes)Ni(CF 3 ) 3 ] − and [( F -NHC)Ni(R f ) 3 ] − ( F -NHC = fluorinated NHC) were synthesized and fully characterized.
Topics & Concepts
IMesCarbeneChemistryCyclic voltammetryLigand (biochemistry)ElectrochemistryTrifluoromethylRedoxMedicinal chemistryRadicalStereochemistryInorganic chemistryCatalysisPhysical chemistryOrganic chemistryElectrodeBiochemistryAlkylReceptorN-Heterocyclic Carbenes in Organic and Inorganic ChemistryFluorine in Organic ChemistryCyclopropane Reaction Mechanisms