Fabrication of rapid response self-powered photodetector using solution-processed triple cation lead-halide perovskite
Geoffrey Ryan Adams, Vincent Obiozo Eze, Md Abu Shohag, Ryan James Simpson, Helen E. Parker, Okenwa I. Okoli
Abstract
Abstract Self-powered photodetectors (PDs) are suitable for application in smart systems, image sensing and optical communications. Herein, a self-powered PD based on triple cation lead-halide perovskite (TCLP) is reported. We showed the effect of bromide concentration on the optical and structural properties of the TCLP films. Additionally, an environmental stability test was conducted and it was found that TCLP with 10% Br can remain stable for up to 128 days after exposure to ambient air. Using this material, a self-powered perovskite PD was fabricated and demonstrated an impressive performance with a responsivity of 0.52 A W −1 , detectivity of 8.8 × 10 12 Jones, on/off ratio of 7.3 × 10 5 , and a rapid rise and decay time of 19 μ s and 21 μ s, respectively. This work offers a useful insight into the effects the fabrication method of the thin film plays in building low-cost, stable, and high-performance self-powered PDs for application in structural health monitoring, imaging, optical communication, and biomedical sensing.