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A Complete Picture of Cation Dynamics in Hybrid Perovskite Materials from Solid-State NMR Spectroscopy

Aditya Mishra, Michael A. Hope, Michaël Grätzel, Lyndon Emsley

2022Journal of the American Chemical Society47 citationsDOIOpen Access PDF

Abstract

, which was found to result from physical diffusion to paramagnetic defects. This precise picture of cation dynamics will enable better understanding of the relationship between the organic cations and the optoelectronic properties of perovskites, guiding the design principles for more efficient perovskite solar cells in the future.

Topics & Concepts

ChemistryNuclear magnetic resonance spectroscopySolid-state nuclear magnetic resonanceSolid-stateSpectroscopyPerovskite (structure)Chemical physicsDynamics (music)Physical chemistryNuclear magnetic resonanceCrystallographyOrganic chemistryQuantum mechanicsAcousticsPhysicsPerovskite Materials and ApplicationsSolid-state spectroscopy and crystallographyAdvanced NMR Techniques and Applications
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