Silylation of silanols with hydrosilanes <i>via</i> main-group catalysis: the synthesis of unsymmetrical siloxanes and hydrosiloxanes
Krzysztof Kuciński, Hanna Stachowiak, Grzegorz Hreczycho
Abstract
Apart from some specific synthetic solutions, a dehydrogenative coupling of silanols with hydrosilanes seems to be the most atom-economical and practical method for the formation of unsymmetrical siloxanes.
Topics & Concepts
SilylationCatalysisChemistryGroup (periodic table)Atom (system on chip)Polymer chemistryOrganic chemistrySiloxaneCombinatorial chemistryComputer scienceEmbedded systemPolymerOrganoboron and organosilicon chemistryCatalytic Cross-Coupling ReactionsSilicone and Siloxane Chemistry