Anion–π interaction inside the polyanionic Mo<sub>132</sub>O<sub>372</sub> cage with hydrophobic inner space
Chinatsu Murata, Jaesob Shin, Katsuaki Konishi
Abstract
cage with a hydrophobic inner nanospace has a unique capability to participate in anion-π interactions by showing a preference for electron-deficient mono-substituted benzenes over non-electron-deficient guests in inclusion.
Topics & Concepts
CageIonCrystallographyChemistrySpace (punctuation)StereochemistryMaterials scienceOrganic chemistryComputer scienceMathematicsCombinatoricsOperating systemMetal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications