Fluoride anion complexation and transport using a stibonium cation stabilized by an intramolecular PO → Sb pnictogen bond
Vanessa M. Gonzalez, Gyeongjin Park, Mengxi Yang, François P. Gabbaı̈
Abstract
A newly synthesized stibonium cation stabilized by an intramolecular PO → Sb pnictogen bond readily transports fluoride anions across phospholipid bilayers.
Topics & Concepts
FluorideChemistryPnictogenIntramolecular forceLewis acids and basesMedicinal chemistryIonBase (topology)Inorganic chemistryStereochemistryOrganic chemistryCatalysisSuperconductivityPhysicsMathematicsMathematical analysisQuantum mechanicsFluorine in Organic ChemistryMolecular Sensors and Ion DetectionInorganic Fluorides and Related Compounds