Evaluation of mechanical, optical, and antibacterial properties of metal‐oxide dispersed <scp>HDPE</scp> nanocomposites processed by rotational molding
Barmak Ghanbarpour, Amin Moslemi
Abstract
Abstract To investigate the impact of zinc oxide/titanium dioxide nanoparticles on the characteristics of high‐density polyethylene, researchers used the rotational molding technique to produce polymeric nanocomposites. The nanocomposites' morphological, mechanical, optical, as well as biological characteristics, were studied using a range of characterizations. SEM analysis revealed a uniform morphology of ZnO and TiO 2 nanoparticles in the polymer matrix, with 80–120 nanometers middle particle dimensions. The existence of ZnO with hexagonal wurtzite form as well as TiO 2 with rutile phase was verified by XRD and XRF. Corresponded to the pure polymer, the HDPE‐ZnO/TiO 2 nanocomposites' flexural modulus and tensile strength increased, but elongation at break reduced, according to mechanical characterization. UV–visible spectroscopy revealed that the HDPE‐ ZnO/TiO 2 nanocomposites showed UV light absorption at wavelengths ranging from 250 to 390 nm. According to antibacterial tests and contact angle measurements, adding metal oxide NPs to HDPE improved hydrophilicity and antibacterial activity.