Photoinduced remote heteroaryl migration accompanied by cyanoalkylacylation in continuous flow
Xiu Duan, Qi Sun, Xin Yuan, Long‐Zhou Qin, Xinpeng Zhang, Jie Liu, Meng‐Yu Wu, Shan‐Shan Zhu, Canliang Ma, Jiang‐Kai Qiu, Kai Guo
Abstract
We have reported a photocatalyzed C–C bond cleavage/C–N bond formation cyanoalkylacylation reaction through the remote C -center to N -center heteroaryl migration under mild conditions using the microflow technique.
Topics & Concepts
Flow (mathematics)Continuous flowChemistryPhotochemistryPhysicsMechanicsRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsOxidative Organic Chemistry Reactions