DMSO/<i>t</i>BuONa/O<sub>2</sub>-mediated efficient syntheses of diverse quinoxalines through α-imino radicals
Chihong Zhang, Zhen Zhang, Deliang Wang, Wenkun Wang, Bo Jin, Tao Wen, Lihua Ye, Zhong‐Ning Chen, Hu Cai
Abstract
system as a single-electron oxidant to form α-imino radicals and nitrogen radicals for the direct construction of C-N bonds. This methodology provides a novel approach to form α-imino radicals with good reactivity.
Topics & Concepts
RadicalReactivity (psychology)ChemistryNitrogenCombinatorial chemistryStereochemistryOrganic chemistryAlternative medicineMedicinePathologySynthesis and Biological EvaluationRadical Photochemical ReactionsCatalytic C–H Functionalization Methods