Porous supramolecular gels produced by reversible self-gelation of ruthenium-based metal–organic polyhedra
Javier Troyano, Fuerkaiti Tayier, Phitchayapha Phattharaphuti, Takuma Aoyama, Kenji Urayama, Shuhei Furukawa
Abstract
-potential, pH, and dynamic light scattering measurements. This strategy leads to the evolution of hierarchically porous aerogel from individual MOP molecules without using any additional component. Furthermore, we demonstrate that the simplicity of this method can be exploited for the obtention of MOP-based gels through a one-pot synthetic approach starting from MOP precursors.
Topics & Concepts
Supramolecular chemistryColloidPorosityCationic polymerizationValence (chemistry)PolyhedronMaterials scienceSelf-assemblyChemical engineeringNanoparticleMoleculeAerogelDynamic light scatteringAqueous solutionNanotechnologyChemistryPolymer chemistryOrganic chemistryMathematicsEngineeringGeometrySupramolecular Self-Assembly in MaterialsPickering emulsions and particle stabilizationCovalent Organic Framework Applications