Li-Free ternary sulphide Cs<sub>5</sub>Ga<sub>9</sub>S<sub>16</sub> with excellent nonlinear optical performance similar to classic LiGaS<sub>2</sub>
Jin-Xu Zhao, Xiao‐Ming Jiang, Wen‐Fa Chen, Shao‐Min Pei, Bin‐Wen Liu, Guo‐Cong Guo
Abstract
The most electropositive element, Cs, was introduced into [Ga 9 S 16 ] 5− framework to acquire the noncentrosymmetric sulphide Cs 5 Ga 9 S 16 , displaying outstanding optical performance when avoided the problem of silica tube corrosiveness similar to LiGaS 2 .
Topics & Concepts
Ternary operationMaterials scienceNonlinear opticalNonlinear systemMetallurgyCrystallographyChemistryComputer sciencePhysicsQuantum mechanicsProgramming languageChalcogenide Semiconductor Thin FilmsCrystal Structures and PropertiesQuantum Dots Synthesis And Properties