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Schottky and Ohmic Contacts at α-Tellurene/2D Metal Interfaces

Youxi Wang, Hao Yuan, Zhenyu Li, Jinlong Yang

2022ACS Applied Electronic Materials24 citationsDOI

Abstract

Tellurene, a two-dimensional (2D) atomic crystal, has been suggested to be a promising channel material. To construct high-performance tellurene-based field effect transistors, a suitable metal electrode should be used. It is desirable that the metal electrode forms an Ohmic contact with tellurene or at least the corresponding contact only has a low Schottky barrier. In this study, properties of interfaces between α-tellurene and a series of 2D metals are explored via first-principles calculations. It is revealed that NbS2 and TaS2 can form p-type Ohmic contacts with monolayer α-tellurene. OH-terminated M3C2 (M = Hf, Nb, Ti, V, Zr) can be adopted to form n-type Ohmic contacts. Interlayer spacing can be used as an effective method to tune the tunneling probability. These findings provide useful insights in understanding the α-Te/2D metal interface and give a practical guidance on electrode selection.

Topics & Concepts

Ohmic contactMaterials scienceElectrodeMonolayerQuantum tunnellingSchottky barrierMetalSchottky diodeOptoelectronicsContact resistanceNanotechnologyChemistryLayer (electronics)MetallurgyPhysical chemistryDiode2D Materials and ApplicationsGraphene research and applicationsAdvanced Thermoelectric Materials and Devices
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